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Linear Combination of Atomic Orbitals - an... | ScienceDirect Topics In the linear combination of atomic orbital (LCAO) approximation (Wallace 1947), the dispersion of these two bands in the two-dimensional reciprocal space of the wave In a minimum basis set, only enough AOs are used to contain the electrons of the core and valence orbitals of the neutral atoms. Atomic Orbital Diagram For Chlorine - Free Catalogs A to Z An orbital diagram is a sketch which shows electron population in atomic orbitals with the electrons spin indicated by up and down arrows. Show transcribed image text create the atomic orbital diagram for chlorine. Valence bond theory and molecular orbital theory The chlorine atoms are connected to the central phosphorus atom. Cl Cl P Cl Cl Cl The molecule has a total of 40 valence electrons. 26. Draw and label a molecular orbital energy diagram to show how two complete sets of 2p atomic orbitals combine to form molecular orbitals. Atomic orb...